郑怀文, 蓝鼎, 王育人. 胶体自组装过程中的形核与绕流影响[J]. 力学与实践, 2011, 33(2): 8-11. DOI: 10.6052/1000-0879-lxysj2010-227
引用本文: 郑怀文, 蓝鼎, 王育人. 胶体自组装过程中的形核与绕流影响[J]. 力学与实践, 2011, 33(2): 8-11. DOI: 10.6052/1000-0879-lxysj2010-227
THE FLOW AROUND NUCLEATION SITES IN COLLOIDAL ASSEMBLING PROCESS$[J]. MECHANICS IN ENGINEERING, 2011, 33(2): 8-11. DOI: 10.6052/1000-0879-lxysj2010-227
Citation: THE FLOW AROUND NUCLEATION SITES IN COLLOIDAL ASSEMBLING PROCESS$[J]. MECHANICS IN ENGINEERING, 2011, 33(2): 8-11. DOI: 10.6052/1000-0879-lxysj2010-227

胶体自组装过程中的形核与绕流影响

THE FLOW AROUND NUCLEATION SITES IN COLLOIDAL ASSEMBLING PROCESS

  • 摘要: 应用长工作距显微镜对胶体粒子自组装过程中初形核阶段进行了原位观察实验研究, 并结合三相接触线附近流场的数值模拟结果对绕流的影响进行了研究. 研究表明流线在短链附近发生弯曲. 当颗粒靠近短链附近时, 水平流将颗粒推向短链的端部. 绕流将抑制形核过程中局部的过快生长, 从而保持生长前沿平直.

     

    Abstract: An in-situ observation of the initial nucleation ofthe colloidal crystal was performed by utilizing a long working distancemicroscope. The streamlines in the vicinity of the three-phase contact lineare calculated by the fluid dynamics software Fluent. The trajectory of theparticle indicates that the streamline is bent around short chains. Whenthe particle goes close to a short chain, a horizontal flow pushes theparticle to the end of the short chain (flowing-around, FA). The simulationindicates that the particles have the abilityof self-adjusting when they are assembled into a colloidal crystal. The FA wouldinhibit too fast growth in a local area, which would lead to a straightgrowth front. This study provides an insight into theself-assembling dynamics and the nucleation process for colloidalcrystal growth.

     

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